What counts is mainly the total resistive load. Volume or tone pots make little difference here when it comes to measured resonant frequencies (at least when pots are full up).
See below.
I've used my "Humbucker as a transformer" model. In this case, it models a HB with 2 conductors cables, symetrical coils, 4.4H, 8k (in the P.A.F. range, IOW).
The curves translate voltage and not current. Otherwise they would be flat before resonant frequency.
Upper left pic = HB with a single 500k volume control.
Bottom left = the same with a single 250k volume pot.
Upper right = the same with a single 25k volume pot.
Bottom right = the same with a 500k volume pot and a 500k linear tone control, itself lowered at 5% of its value. There's a slight shift of the "frequential dome" obviously due to the tone cap (whose capacitance
really enters in the game when the pot is set really, really low, for the record, albeit it can affect harmonics even when pots are full up).
If we wanted the load to be exactly @ 25k, the tone pot would be to set @ approximatively 5.3% of its value.
So and to sum it up, a single 25k pot would behave largely like a guitar with two 500k pots, whose tone control would be set just above the final shift to a second resonant frequency caused by the cap...
FWIW, I've once mounted a 25k tone pot instead of a 250k because of a stupid error (not a good idea for a senior to solder in the dark)... The HB was a bright and powerful HB with ceramic mag. The tone was dull (and made me realize my mistake) but it was not as dark as I would have expected...
NOTE - 5spice sims done and pic assembled while I was sipping my morning coffee. To take with a grain of salt, so (the pic and not the coffee). ;-P
