Well, the high voltage isn't hitting your tubes until you take it off standby- so I don't see all that much to be gained by warming the amp on standby for extended lengths. They are only gonna warm up to a certain temp on standby, but, will get much warmer after you take it off standby.
Most class A amps don't have a standby switch- and they generally run hotter by nature.
My tube amps do sound better after I've played them for at least 1/2 hour, then they kinda hit the sweet spot. (or, is it that our ears becoming used to it?)