Thanks for the info, everybody. To clarify why I was asking the question:
I have a humbucker guitar with 2 volumes and 1 master tone. The volume pots are 250K. The tone is 500K.
I was considering swapping out the 250K volumes for 500K volumes, but then I thought about how I almost never use the tone pot. And how it would be easier/less expensive to swap one pot instead of two. So I modded the stock 500K to be a no load tone pot.
Here is a summary of the options I've considered:
Stock setup "A" with controls at 10 was: 250K vol in parallel with 500K tone = 167K + the effects of the capacitor.
Modified setup "B" with controls at 10 is: 250K vol in parallel + no load tone pot = 250K (and no effect from the capacitor). This is the way I currently have it setup.
Modified setup "C" with controls at 10: 500K vol + 500K tone = 250K + the effects of the tone capacitor.
Modified setup "D" with controls at 10: 500K vol + no load tone pot = 500K (and no effect from the capacitor).
Thinking out loud, I would venture to guess going from brightest to darkest it would go: D, B, C, A.
Sound correct?