Turning the volume down on one pup doesn't put them "in phase". Being out of phase is a physical/mechanical condition concerning how 2 pups are related to each other. To be OOP, either one pup has the reverse wiring of another or it has reverse magnetic polarity of the other. The effect is a cancellation of certain frequencies of waves which is most effective when the two pups are contributing equally to the total output of the sound (the "volume balance" that you refer to). If you reduce the signal of one of the pups there will be less cancellation of those specific frequencies and the "sound" will become more "normal", like just playing one pup, but the two pups are still OOP. Like if you switch to either the neck or the bridge pup it will sound like the normal neck or bridge pup even though your two pups are still OOP.
You don't need to drill any holes to add a switch to toggle between in phase and out of phase. You can just replace one of your volume controls with a push/pull pot. When in the normal "down" position you will be in phase. When you pull the volume knob up, it will actually reverse the wiring of one pup so you will actually be out of phase. Simple. And then you will have both tones available.