If you have two output jacks, you cold do two 16 ohm pairs
So if I have a 16-ohm head and an 8-ohm cab what are my options. And is there a way to wire up four 8-ohm speakers for 16 ohms?

Right. This thread had me confused at first, until the following clarification was made (which must have been while I was typing my first response).Two pairs in parallel? That won't give you 16 ohms total.
So the initial post stating the amp was 16 ohms was misleading. It obviously is 8 ohm (via 2 parallel 16 ohm inputs) I think?There are two 16 ohm outputs on the amp what are you suggesting?
There are two 16 ohm outputs on the amp. I want to avoid wiring it for stereo because I would have to hack a vintage plate on the back of the cab. The head is a AMPEG B-25b.
The extension speaker jack opens up the 8 ohm tap.